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Thursday, May 20, 2010

Oxides of rare earth metals

I am glad to be back after the long break as there are several interesting issues on which I would like to comment.
 
First, in the spirit of my earlier post (”
Era of materials and elaborate material systems” of January 12, 2010) a quick observation with regard to the still expanding pool of elements from which semiconductor researchers and engineers are drawing to build better performing devices. Most you may not remember it, but, as I was commenting earlier, for years it was all about silicon, oxygen, nitrogen, and aluminum. It was all that was needed to fabricate most of the devices including early ICs. Then the copper joined in, then … Well, as the needs are growing and complexity of devices increases rapidly, it seems as almost every element in the periodic table is of potential interest to the semiconductor community these days.

 
Let’s consider gate dielectrics for instance. After exploring transition metals oxides (e.g. HfO2, ZrO2 TiO2, Ta2O5 etc.), and focusing attention on hafnia, the search for yet the other substitutes for the SiON based dielectrics digs even deeper into the periodic table. Oxides of rare earth metals consisting mostly of lanthanides (look for them at the bottom of the periodic table) attracted a great deal of attention recently.


How about gadolinium oxide (Gd2O3 ) also know as gadolinia? To the old-time “semiconductorer” such as me it sounds rather exotic. I will be back with some more specific comments on gadolinia soon.

Posted by Jerzy Ruzyllo at 07:08 PM | Semiconductors | Comments (7) | Link


Comments

Posted by Anonymous  on Saturday, May 22, 2010 09:49 PM | #
Dear Dr. Ruzyllo, Welcome back from the sabbatical. Wi
th all due respect I would like to suggest a correction....G
adolinium oxide is Gd2O3. Eagerly looking forward to your
comments on this rare-but-interesting oxide.

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Posted by J. Ruzyllo  on Monday, May 24, 2010 12:32 PM | #
Ooooops, a typo... thanks!
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Posted by sandy  on Wednesday, May 26, 2010 11:13 AM | #
Great article!
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Posted by Mike from California  on Sunday, May 30, 2010 10:23 PM | #
Good that you are back. Your postings help me understand wha
t''s going on in the world of semiconductor.

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Jerzy Ruzyllo is a Distinguished Professor of Electrical Engineering and Professor of Materials Science and Engineering at Penn State and in his spare time he likes to blog about semiconductors and related topics.


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Recent posts
Interesting times
Is there enough gallium?
Nanotechnology - "hard" and "soft"
Cheap, highest quality substrate?
Nano-ordered semiconductors
Gadolinia story
Oxides of rare earth metals
On sabbatical
Era of materials and elaborate material systems
Graphene comes to life


Categories
Semiconductors





Copyright © 2010 J. Ruzyllo. All rights reserved.